Winds 285 degrees at 8 m/s, pressure 1006.7 and rising, partly
cloudy, dry bulb 10.2C, wet bulb 8.0C seawater 10.2C.
SEA STATE:
Westerly 2-3 M swell, wind waves from 290 at 1 M
INSTRUMENTS/SYSTEMS STATUS
Sea Surface Measurements:
DMS: Current concentration 1.3nM
DMSP/DMSO:
Samples collected every 8 hours for particulate and dissolved DMSP and
DMSO.
NH4+NH3/pH:
CO:
Surface seawater concentrations have a diurnal cycle with a late night
minimum of 0.8 and and an afternoon maximum of 1.2 nM.
NMHC:
Butane ~2ppb; Pentane ~0.4ppb in equilibrated air samples.
CO2:
Nitrate/Chlorophyll:
Nitrate concentrations are approx 6.4 uM.
Seawater fluorescence is being recorded continuously.
Surface seawater samples are being collected every 4 hours
for discrete chlorophyll analysis.
Atmospheric Measurements:
DMS:
Current concentrations at 45S are approximately 80 ppt.
SO2:
Concentrations have increased from approximately 5 to 10 ppt.
NH3:
Using oxalic acid coated filters. Concentrations measured with oxalic
acid coated filters range from 3 to 10 pptv.
CO:
Concentrations near 60ppb.
NMHC:
Butane ~8ppt; Pentane ~1ppt
O3:
Concentrations range from 18-24 ppb.
Nitrogen oxides and PAN:
NO<4 ppt and NOy ~300 ppt.
NO2 not operational.
Aerosol chemistry:
2-stage and 7-stage impactors currently sampling for time
periods ranging from 24 to 72 hours for IC, total organic carbon, speciated
organics, and gravimetric analysis.
System operational with 4 sondes/day. Extra sondes were launched at 0800
1400, and 2000 to support Lagrangian #2.
Routine Weather Observations: Going well.
Satellite Observations: None
CTD Cast Schedule: None.
SPECIAL PLANNED OBSERVATIONS (NEXT 24-HOURS):
At 2100 the ship will turn downwind and sample seawater along the
Lagrangian path for DMS and NH3 concentrations. Every 4 hours the ship
will turn bow to wind for 30 minutes of air sampling.
PAST 24-HR OPERATIONS SUMMARY:
The primary objective yesterday was to keep the wind within 45 degrees of
the bow for clean SO2 sampling. In addition we tried to steam southward
to cross the oceanic front at approximately 46S. Due to wind conditions we
were unable to accomplish the second objective.
At 0900 the ship held station (45S, 141E) to prepare for the second
Lagrangian. Extra sondes were launched and a smart balloon (#10) was
launched at 1245. A second smart balloon launch at 1400 (#4) was
unsuccessful. The ship held station after the balloon launches for air and
surface seawater sampling. There was no indication of ultra-fine partilces
mixing into the boundary layer after frontal passage.
OTHER COMMENTS:
. We did not receive the operations summary yesterday and would still
appreciate a copy for our records.