Winds 010 degrees at 9 m/s, pressure 1003.0 and falling, overcast
with periods of drizzle, dry bulb 12.0C, wet bulb 11.0C, SST 11.6
SEA STATE:
Southwesterly 2-3 M swell, wind waves from 010 at 1 M
INSTRUMENTS/SYSTEMS STATUS
Sea Surface Measurements:
DMS: Current concentration 1-3nM
DMSP/DMSO: Dissolved
DMSPconcentrations are about 5 nM, particulate DMSP about 15 nM.
Incubation from 12/03 showed 15 hour turnover time for DMSP.
NH4+NH3/pH:
CO:
Surface seawater concentrations have a diurnal cycle with a late night
minimum of 1 and and an afternoon maximum of 2 nM.
NMHC:
Low ppb levels of butane. sub ppb levels of pentane in equilibrated air
samples.
CO2:
Nitrate/Chlorophyll:
Nitrate concentrations are approximately 3 uM.
Seawater fluorescence is being recorded continuously.
Surface seawater samples are being collected every 4 hours
for discrete chlorophyll analysis.
Atmospheric Measurements:
DMS:
Initial concentrations at frontal passage of approximately 200 ppt
dropped steadily through the day to 50 ppt.
SO2:
Concentrations range from 10 to 30 ppt.
NH3:
Using oxalic acid coated filters.
CO:
Concentrations near 60ppb.
NMHC:
ppt levels of a few hydrocarbons. very clean air.
O3:
Surface concentrations are in the 15 to 20 ppb range.
An ozonesonde was launched between the second and third
smart balloon launchs which gave an ozone profile to 34 km.
Ozone mixing ratios were 17-20 ppb below 1.4km and in the
high 20's and low 30's in the 2km above the boundary layer
inversion.
Nitrogen oxides and PAN:
NO max ~2pm lt at ~10ppt; NO2 steady 10-12 ppt,
NOy ~600 ppt AM but maxed at ~900ppt about 2pm.
PAN not operaterational.
Radon:
CO2:
Solar Radiation:
Aerosol physics:
Aerosol chemistry:
2-stage and 7-stage impactors currently sampling for time periods
ranging from 24 to 72 hours for IC, total organic carbon, speciated
organics, and gravimetric analysis.
Aerosol optical properties.
TDMA-RH: During the last few days we
have observed several occasions with low growth factors ~1.4, as we move
into high pressure regions.
Continue sampling at Lagrangian start point until air mass changes to
continental. Discoverer will then follow the smart balloon track to measure
surface seawater DMS and NH3 concentrations.
PAST 24-HR OPERATIONS SUMMARY:
Discoverer passed in and out of the front several times as we were guided to
the smart balloon launch point. Three balloons were successfully launched
to mark the third and final Lagrangian air mass. Air and surface seawater
sampling continued at the final launch location for the remainder of the day.